An atom trap system for ³⁹Ar dating with improved precision

Cosmogenic ³⁹Ar dating is an emerging technique in dating mountain glacier ice, mapping ocean circulation, and tracing groundwater flow. We have realized an atom-trap system for the analysis of the radioactive isotope ³⁹Ar (half-life = 269 years) in environmental samples. The system is capable of analyzing small (1-5 kg) environmental water or ice samples and achieves a count rate of 10 atoms/h for ³⁹Ar at the modern isotopic abundance level of 8 × 10^-16. By switching frequently between counting ³⁹Ar atoms and measuring the stable and abundant isotope ³⁸Ar, drift effects in the trapping efficiency are largely suppressed, leading to a more precise measurement of the isotope ratio ³⁹Ar/³⁸Ar. Moreover, cleaning techniques are developed to alleviate cross-sample contamination, reducing the background ³⁹Ar count rate down to <0.5 atoms/h. These advances allow us to determine the ³⁹Ar age in the range of 250-1300 years with precisions of <20%.