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Bioinspired Photoredox Benzylation of Quinones

Maxime Donzel1, Mourad Elhabiri1, Elisabeth Davioud-Charvet1

  • 1Laboratoire d'Innovation Moléculaire et Applications (LIMA) Team Bio(IN)organic and Medicinal Chemistry, European School of Chemistry, Polymers and Materials (ECPM), Université de Strasbourg-CNRS-UHA UMR7042, 25 Rue Becquerel, Strasbourg 67087, France.

The Journal of Organic Chemistry
|July 15, 2021
PubMed

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In the presence of oxidizing agents, phenols are oxidized to quinones. Quinones can be easily reduced back to phenols using mild reducing agents. The electron-donating hydroxyl group enhances the reactivity of the aromatic ring, enabling oxidation of the ring even in the absence of an α hydrogen.
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