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Related Concept Videos

Types of Coprecipitation01:10

Types of Coprecipitation

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Coprecipitation is the contamination of a precipitate by otherwise soluble species and occurs via different processes. In colloidal precipitates, coprecipitation occurs via surface adsorption. For instance, barium sulfate has a primary layer of adsorbed barium ions and a secondary layer of nitrate counterions. This results in contamination of the precipitate by barium nitrate.
Sometimes, ions in a crystal lattice can undergo isomorphous replacement by inclusions of similar charge and size. For...
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After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...
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Precipitation Processes

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The experimental conditions in a gravimetric analysis should be optimized to maximize the particle size and purity of the obtained precipitate. Ideally, the concentration of the precipitating reagent should be low with effective stirring to maintain low relative supersaturation for the growth of large crystals. In homogeneous precipitation, the precipitant is slowly generated by a chemical reaction in the solution to avoid local reagent excesses. For example, urea decomposes gradually to...
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Creating Two-Dimensional Patterned Substrates for Protein and Cell Confinement
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Patterns from drops drying on inclined substrates.

P Logesh Kumar1, Sumesh P Thampi, Madivala G Basavaraj

  • 1Department of Chemical Engineering, Polymer Engineering and Colloid Sciences Laboratory, Indian Institute of Technology Madras, Chennai-600036, India. basa@iitm.ac.in sumesh@iitm.ac.in.

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Summary
This summary is machine-generated.

Gravity breaks coffee ring symmetry in drying droplets. Particle deposition asymmetry increases with lower substrate wettability and depends non-monotonically on substrate inclination, revealing new transport mechanisms.

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Area of Science:

  • Colloid science
  • Fluid dynamics
  • Materials science

Background:

  • The coffee ring effect describes particle deposition at the edge of drying droplets.
  • Evaporation-driven capillary flow typically leads to symmetrical particle patterns.
  • Gravity can break this symmetry by tilting the substrate.

Purpose of the Study:

  • To investigate how particle size, substrate wettability, and inclination angle influence asymmetry in drying droplet patterns.
  • To explore additional particle transport mechanisms beyond evaporation-driven flow.

Main Methods:

  • Experiments involving drying aqueous dispersions of polystyrene particles on inclined substrates.
  • Varying particle sizes, substrate wettability, and substrate inclination angles.

Main Results:

  • Particle deposition asymmetry was observed regardless of particle size.
  • Increased asymmetry correlated with decreased substrate wettability.
  • The degree of asymmetry showed a non-monotonic relationship with the substrate inclination angle.

Conclusions:

  • Gravity, wettability, and inclination angle significantly impact particle distribution in drying droplets.
  • Evaporation-driven capillary flow is not the sole mechanism; other transport phenomena are involved.
  • Further research is needed to understand pattern formation physics on oriented substrates.