Ultrathin Reduced Graphene Oxide/Organosilica Hybrid Membrane for Gas Separation

Here, reduced graphene oxide (r-GO) nanosheets were embedded in an organosilica network to assemble an ultrathin hybrid membrane on the tubular ceramic substrate. With the organosilica nanocompartments inside the r-GO stacks and the intensified polymerization, r-GO sheets endow the as-prepared hybrid membranes with high H₂ and CO₂ separation performance. The resulting selectivities of H₂/CH₄ and CO₂/CH₄ are found to be 223 and 55, respectively, together with gas permeance of approximately 2.5 × 10^-7 mol·m^-2·s^-1·Pa^-1 for H₂ and 6.1 × 10^-8 mol·m^-2·s^-1·Pa^-1 for CO₂ at room temperature and 0.2 MPa. To separate larger molecules from H₂, the H₂/C₃H₈ and H₂/i-C₄H₁₀ selectivities are as high as 1775 and 2548, respectively. Moreover, at 150 °C and 0.2 MPa, the hybrid membrane retains high separation performances with ideal selectivities higher than 200 and 30 for H₂/CH₄ and CO₂/CH₄, respectively, which are attractive for gas separation and purification of practical applications.