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Updated: Oct 19, 2025

Monolayer Contact Doping of Silicon Surfaces and Nanowires Using Organophosphorus Compounds
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Controllable Doping in 2D Layered Materials.

Zhen Wang1,2, Hui Xia1,2, Peng Wang1,2

  • 1State Key Laboratory of Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai, 200083, China.

Advanced Materials (Deerfield Beach, Fla.)
|September 27, 2021
PubMed
Summary

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This summary is machine-generated.

Controlling semiconductor doping is key for electronics. This study reveals thickness-tuning of 2D materials like PtSSe and WSe2 enables precise p-type, intrinsic, and n-type doping for advanced devices.

Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Semiconductor doping is crucial for electronic and optoelectronic applications.
  • Controllable doping of 2D materials presents significant challenges.
  • Existing methods lack continuous control over doping types (p-type, n-type).

Purpose of the Study:

  • To report a novel self-modulated doping characteristic in 2D layered materials.
  • To demonstrate controllable doping by varying the number of stacked monolayers.
  • To explore thickness-induced defect transitions for tuning semiconductor properties.

Main Methods:

  • Investigated 2D layered materials including PtSSe, PtS0.8 Se1.2 , PdSe2 , and WSe2.
  • Utilized varying numbers of vertically stacked monolayers to tune doping.
Keywords:
controllable dopingelectronic materialslattice deformationlayered materialsoptoelectronics

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  • Performed dynamic and thermodynamic analyses to understand defect behavior.
  • Main Results:

    • Demonstrated thickness-modulated doping from p-type to intrinsic to n-type in the same material.
    • Identified thickness-induced lattice deformation causing defect transitions (e.g., Pt vacancies to anion vacancies in PtSSe).
    • Achieved a high rectification ratio (4400) and open-circuit voltage (0.38 V) in WSe2 diodes.
    • Developed PtSSe detectors with reduced dark current for narrow-bandgap applications.

    Conclusions:

    • Thickness-modulated doping offers a new paradigm for 2D semiconductor control.
    • This method provides a pathway for developing high-performance 2D electronic and optoelectronic devices.
    • Findings offer novel perspectives for fundamental research and practical applications in 2D materials.