Core-Shell Structured C@SiO₂ Hollow Spheres Decorated with Nickel Nanoparticles as Anode Materials for Lithium-Ion...

Silicon oxide is regarded as a promising anode material for lithium-ion batteries owing to high theoretical capacity, abundant reserve, and environmental friendliness. Large volumetric variations during the discharging/charging and intrinsically poor electrical conductivity, however, severely hinder its application. Herein, a core-shell structured composite is constructed by hollow carbon spheres and SiO₂ nanosheets decorated with nickel nanoparticles (Ni-SiO₂ /C HS). Hollow carbon spheres, as mesoporous cores, not only significantly facilitate the electron transfer but also prominently enhance the mechanical robustness of anode materials, which separately improves the rate performance and the cyclic durability. Besides, ultrathin SiO₂ nanosheets, as hierarchical shells, provide abundant electrochemical active surface for capacity increment. Moreover, nickel nanoparticles boost the transport capacity of electrons in SiO₂ nanosheets. Such a unique architecture of Ni-SiO₂ /C HS guarantees an enhanced discharge capacity (712 mAh g^-1 at 0.1 A g^-1 ) and prolonged cyclic durability (352 mAh g^-1 at 1.0 A g^-1 after 500 cycles). The present work offers a possibility for silica-based anode materials in the application of next-generation lithium-ion batteries.