s-Block chemistry in weakly coordinating solvents

Alkaline earth metal catalysis has been a growing field in recent years. To enhance reactivity and to understand the metal-substrate interactions in more detail, reactions are increasingly carried out in weakly coordinating solvents. This article gives an overview over the two main approaches to facilitate this, which are either through the employment of highly dipolar haloaryls as solvents, or by increasing the solubility of the ligand systems. The resulting coordination modes and reactivities are presented together with the synthetic strategies. Additionally, the latest results of group 1 complex chemistry in aliphatic solvents are illustrated and future challenges are highlighted.