Related Experiment Video
Updated: Oct 10, 2025

06:27
Expression of Cementitious Pore Solution and the Analysis of Its Chemical Composition and Resistivity Using X-ray Fluorescence
Published on: September 23, 2018
9.4K
Performance Testing of Hydraulic Cements: Measuring Sulfate Resistance.
Chiara F Ferraris1, Paul E Stutzman1, Max Peltz1
1National Institute of Standards and Technology, Gaithersburg, MD 20899, USA.
Summary
A new, faster cement sulfate resistance test uses smaller samples to achieve results in under 3 months, compared to the traditional year-long method. This allows quicker evaluation of innovative cementitious materials.
Area of Science:
- Materials Science
- Civil Engineering
- Construction Materials
Background:
- Traditional cement sulfate resistance testing is lengthy, taking over a year.
- The extended duration hinders the evaluation of novel cementitious materials.
Purpose of the Study:
- To develop a rapid test method for assessing cement sulfate resistance.
- To reduce the testing time for cementitious materials significantly.
Main Methods:
- A new test method was developed by the National Institute of Standards and Technology (NIST).
- The method utilizes smaller cement paste bars (10 mm × 10 mm × 60 mm).
- Expansion of these smaller bars in sodium sulfate solution is measured.
Main Results:
- Similar expansion to the traditional method is achieved in less than 3 months.
- The test duration is reduced by a factor of at least 4.
- The accelerated method yields results consistent with traditional procedures.
Conclusions:
- The developed accelerated test method allows for rapid results in cement sulfate resistance assessment.
- This shorter decision time facilitates the screening of a wider range of innovative materials.
- The NIST-developed method enhances performance-based determination of cementitious materials.
More Related Videos
Related Concept Videos
Sulfate Attack on Concrete
335
Sulfate attack on concrete is a deterioration process characterized by a whitish discoloration beginning at the edges and corners, accompanied by cracking and spalling. This phenomenon occurs when sulfates react with the components of hardened concrete, forming compounds like calcium sulfate and calcium sulfoaluminate which occupy more space than the substances they replace, causing the concrete to expand and disrupt.
Sulfates from sources like soil, groundwater, or industrial effluents...
Sulfates from sources like soil, groundwater, or industrial effluents...
335
Strength of Cement
240
Strength tests for cement are not performed directly on neat cement paste due to difficulty in obtaining consistent, reliable specimens. Instead, cement is typically tested in the form of cement-sand mortar.
For compressive strength tests, ASTM C 109-05 standards prescribe a cement-sand mix ratio of 1:2.75 and a water/cement ratio of 0.485 for making 2-inch cubes. These cubes are mixed, cast, and cured in saturated lime water at 23°C until testing. Flexural strength testing, outlined in...
For compressive strength tests, ASTM C 109-05 standards prescribe a cement-sand mix ratio of 1:2.75 and a water/cement ratio of 0.485 for making 2-inch cubes. These cubes are mixed, cast, and cured in saturated lime water at 23°C until testing. Flexural strength testing, outlined in...
240
Testing Water Quality
208
When the quality of water for concrete preparation is uncertain, its impact on the setting time of cement and compressive strength of mortar is assessed by comparison with de-ionized or distilled water benchmarks. American Society for Testing and Materials (ASTM) C1602 requires the setting times to be within 90 minutes of the control, British Standard (BS) 3146:1980 allows a 30-minute variance in the initial setting, while British Standards European Norm (BS EN) 1008 specifies initial setting...
208
Soundness of Cement
273
The soundness of cement refers to the ability of cement paste to retain its volume after setting. Unsound cement can lead to expansion and structural damage due to the presence of free lime, magnesia, and calcium sulfate. Free lime hydrates very slowly, expanding and causing unsoundness, which is difficult to detect because it intercrystallizes with other compounds. Magnesia also reacts with water, forming crystals that can disrupt the cement's structure. Calcium sulfate can create...
273
Fineness of Cement
258
The fineness of cement directly influences the rate of hydration, as the hydration begins at the surface of the cement particles. In addition to hydration, the fineness of cement is vital for various properties of concrete including workability, gypsum requirement, and long-term behavior. The fineness of cement is represented in terms of the specific surface of cement which is typically measured in square meters per kilogram, with several methods available for this determination.
Direct...
Direct...
258
Strength and Heat of Hydration
381
The hydration of cement is an exothermic reaction in which heat is generated as cement hydrates. This heat of hydration is critical to cement's strength development. The rate at which this heat is generated affects the temperature rise, with a majority of the heat being released early in the hydration process, half within the first three days, and about 75% within the first week.
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
The heat of hydration for each cement compound is significant; for instance, tricalcium aluminate (C3A) and...
381

