Investigation of Mechanical and Magnetic Properties of Co-Based Amorphous Powders Obtained by Atomization

Properties of Co-based alloys with high Glass Forming Ability (GFA) in the form of powder are still not widely known. However, powders of high GFA alloys are often used for the development of bulk metallic glasses by additive manufacturing. In this work Co_47.6B_21.9Fe_20.4Si_5.1Nb₅% at. and Co₄₂B_26.5Fe₂₀Ta_5.5Si₅Cu₁% at. were developed by gas-atomization. Obtained powders in size 50-80 µm were annealed at T_g and T_x of each alloy. Then SEM observation, EDS analyses, differential thermal analysis, X-ray diffraction, nanoindentation, Mössbauer, and magnetic properties research was carried out for as-atomized and annealed states. The gas atomization method proved to be an efficient method for manufacturing Co-based metallic glasses. The obtained powder particles were spherical and chemically homogeneous. Annealing resulted in an increase of mechanical properties such as hardness and the elastic module of Co_47.6B_21.9Fe_20.4Si_5.1Nb₅% at and Co₄₂B_26.5Fe₂₀Ta_5.5Si₅Cu₁%, which was caused by crystallization. The magnetic study shows that Co_47.6B_21.9Fe_20.4Si_5.1Nb₅ and Co₄₂B_26.5Fe₂₀Ta_5.5Si₅Cu₁ are soft magnetic and semi-hard magnetic materials, respectively.