Novel Temperature-Responsive Rosin-Derived Supramolecular Hydrogels Constructed by New Semicircular Aggregates
Zhaolan Zhai1, Shengfeng Ye1, Zhanqian Song1
1Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry; Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Province; Key Laboratory of Biomass Energy and Material, Jiangsu Province; Key Laboratory of Chemical Engineering of Forest Products, National Forestry and Grassland Administration; National Engineering Laboratory for Biomass Chemical Utilization, Nanjing 210042, Jiangsu Province, China.
Abstract:
A highly water-soluble rosin-based surfactant (C14-MPA-Na) was synthesized. Novel temperature-responsive supramolecular hydrogels were further prepared using C14-MPA-Na. The microstructure and the mechanical properties of the hydrogels were investigated. Unexpectedly, instead of the long one-dimensional structure, a new kind of twisted semicircular aggregate was formed in the hydrogels, which was rarely reported. Besides, the hydrogels possessed excellent shear-recovery properties. Upon heating to 40 °C, the hydrogels transformed into viscoelastic solutions, which were constructed by worm-like micelles. By adjusting the temperature, the hydrogels and the viscoelastic solutions could be freely transformed. Nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy were used to further explore the possible self-assembly mechanism of C14-MPA-Na. The curved alkane chain which partially overlapped with rosin's rigid skeleton became stretched when heated to 40 °C. The introduction of the rosin rigid skeleton endowed the supramolecular hydrogels with a novel microstructure and contributed to the development of strategies for the utilization of forest resources.
