CeO₂-Promoted PtSn/SiO₂ as a High-Performance Catalyst for the Oxidative Dehydrogenation of Propane with Carbon...

The oxidative dehydrogenation of propane with CO₂ (CO₂-ODP) has been extensively investigated as a promising green technology for the efficient production of propylene, but the lack of a high-performance catalyst is still one of the main challenges for its industrial application. In this work, an efficient catalyst for CO₂-ODP was developed by adding CeO₂ to PtSn/SiO₂ as a promoter via the simple impregnation method. Reaction results indicate that the addition of CeO₂ significantly improved the catalytic activity and propylene selectivity of the PtSn/SiO₂ catalyst, and the highest space-time yield of 1.75 g(C₃H₆)·g(catalyst)^-1·h^-1 was achieved over PtSn/SiO₂ with a Ce loading of 6 wt%. The correlation of the reaction results with the characterization data reveals that the introduction of CeO₂ into PtSn/SiO₂ not only improved the Pt dispersion but also regulated the interaction between Pt and Sn species. Thus, the essential reason for the promotional effect of CeO₂ on CO₂-ODP performance was rationally ascribed to the enhanced adsorption of propane and CO₂ originating from the rich oxygen defects of CeO₂. These important understandings are applicable in further screening of promoters for the development of a high-performance Pt-based catalyst for CO₂-ODP.