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Updated: Oct 1, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

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Transient chirality inversion during racemization of a helical cobalt(III) complex

Yoko Sakata1,2, Shunsuke Chiba1, Shigehisa Akine1,2

  • 1Graduate School of Natural Science and Technology, Kanazawa University, Kanazawa 920-1192, Japan.

Proceedings of the National Academy of Sciences of the United States of America
|March 8, 2022
PubMed
Summary

Chiral helical complexes unexpectedly inverted their handedness during racemization, forming a hysteretic cycle. This transient chirality inversion offers potential for developing time-programmable switchable materials.

Keywords:
chirality inversionhelical structurehysteretic cycleligand exchangenonlinear kinetics

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