Achievements and Future Perspectives of the Trivalent Thulium-Ion-Doped Mixed-Sesquioxide Ceramics for Laser...

This paper is devoted to reviewing the latest results achieved in solid-state lasers based on thulium-doped mixed-sesquioxide ceramics, i.e., (Lu,Sc,Y)₂O₃. The near- and mid-infrared regions are of interest for many applications, from medicine to remote sensing, as they match molecular fingerprints and cover several atmospheric transparency windows. These matrices are characterized by a strong electron-phonon interaction-which results in a large splitting of the ground state-and by a spectral broadening of the optical transition suitable for developing tunable and short-pulse lasers. In particular, the manuscript reports on the trivalent thulium laser transitions at 1.5, 1.9, and 2.3 µm, along with the thermal and optical characteristics of the (Lu,Sc,Y)₂O₃ ceramics, including the fabrication techniques, spectroscopic and optical properties, and laser performances achieved in different pumping regimes, such as continuous-wave (CW), quasi-CW, and pulsed modes. A comparison of the performance obtained with these mixed-sesquioxide ceramics and with the corresponding crystals is reported.