Understanding Solvothermal Growth of Metal-Organic Framework Colloids for CO₂ Capture Applications

A quantitative study of the synthesis of metal-organic framework (MOF) colloids via a solvothermal growth process was demonstrated using electrospray-differential mobility analysis (ES-DMA), a gas-phase electrophoresis approach. HKUST-1, a copper-based MOF (Cu-MOF), was selected as the representative MOF of the study. The effects of the synthetic parameters, including ligand concentration (C_BTC), synthetic temperature (T_s), and synthetic time (t_s) versus material properties of the Cu-MOF, were successfully characterized based on the mobility size distributions measured by ES-DMA. The results show that the mobility size of Cu-MOF was proportional to T_s, t_s, and C_BTC during the solvothermal growth. X-ray diffraction and Brunauer-Emmett-Teller analyses were employed complementarily to the ES-DMA, confirming that the increase in mobility size of Cu-MOF was correlated to the increase in crystallinity (i.e., larger specific surface area and crystallite size). The results of CO₂ pulse adsorption show that the synthesized Cu-MOF possessed a good CO₂ adsorption ability under 1 atm, 35 °C, and the cumulative amount of CO₂ uptake was proportional to the measured mobility size of Cu-MOF. The work provides a proof of concept for the controlled synthesis of MOF colloids with the support of gas-phase electrophoretic analysis, and the quantitative methodology is useful for the development of MOF-based applications in CO₂ capture and utilization.