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Green synthesis of the battery material lithium sulfide via metathetic reactions

Liran Fang1, Qiaran Zhang1, Aiguo Han1

  • 1Institute of Molecular Plus, Tianjin University, Tianjin 300072, China. xin_zhangtju@tju.edu.cn.

Chemical Communications (Cambridge, England)
|April 13, 2022
PubMed

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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