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Photocatalytic hydrogen evolution based on carbon nitride and organic semiconductors
Hantang Zhang1, Jie Liu2, Lang Jiang2
1College of Chemistry and Material Science, Shandong Agriculture University, Taian 271000, People's Republic of China.
Abstract:
Photocatalytic hydrogen evolution (PHE) presents a promising way to solve the global energy crisis. Metal-free carbon nitride (CN) and organic semiconductors photocatalysts have drawn intense interests due to their fascinating properties such as tunable molecular structure, electronic states, strong visible-light absorption, low-cost etc. In this paper, the recent progresses of photocatalytic hydrogen production based on organic photocatalysts, including CN, linear polymers, conjugated porous polymers and small molecules, are reviewed, with emphasis on the various strategies to improve PHE efficiency. Finally, the possible future research trends in the organic photocatalysts are prospected.
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