An ultrastable Ti-based metallocalixarene nanocage cluster with photocatalytic amine oxidation activity

Polyhedral metallocalixarene nanocage clusters based on pure Ti(IV) ions are to our knowledge unknown hitherto. Herein we report the first Ti(IV)-based metallocalixarene nanocage cluster by assembling a [Ti₁₃O₁₄] cage with six t-butylcalix[4]arene molecules. Notably, the cluster exhibits extraordinary stability in high-concentration acid/alkali solutions and can act as a stable photocatalyst to catalyze the oxidation of ammonia to imines.