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Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
A microwave synthesized mesoporous carbon sponge as an efficient adsorbent for Cr(vi) removal
Yan-Jun Liu1, Shan Liu1, Zhi-Wen Li1
1Engineering Research Center of Forestry Biomass Materials and Bioenergy, Beijing Key Laboratory of Lignocellulosic Chemistry, College of Materials Science and Technology, Beijing Forestry University Beijing 100083 PR China mg_ma@bjfu.edu.cn.
Abstract:
Mesoporous carbon materials have recently attracted immense research interest because of their potential application in water purification fields. Herein, we report the synthesis of a mesoporous carbon sponge (MCS) from a supramolecular microcrystalline cellulose-polymer system triggered by microwave-assisted treatment. Benefiting from the three-dimensional (3D) interconnected mesopores and an evenly distributed ball-like protuberance on the inner surfaces of the macropores, the MCS exhibited a high adsorption capacity (93.96 mg g-1) for fast Cr(vi) removal within 5 min. Additionally, the MCS can be regenerated and reused after the adsorption-desorption process, and maintained an adsorption capacity of ∼86% after 10 cycles. The high adsorption capacity, significantly reduced treatment time, and reusability make the MCS promising for the purification of wastewater on a large scale.

