Effect of Transition Metal Doping on the Structural, Morphological, and Magnetic Properties of NiFe₂O₄

Sol-gel route followed by thermal treatment was used to produce NiFe₂O₄ doped with transition metal ions (Zn²⁺, Mn²⁺, Co²⁺). The structural, morphological, and magnetic properties of the doped NiFe₂O₄ were compared with those of virgin NiFe₂O₄. The metal-glyoxylates' formation and decomposition as well as the thermal stability of the doped and virgin ferrites were assessed by thermal analysis. The functional groups identified by Fourier-transform infrared spectroscopy confirmed the decomposition of metal nitrates, the formation and decomposition of precursors, and the formation of the SiO₂ matrix. The X-ray diffraction indicated that the sol-gel synthesis produced single-phase crystalline ferrites in case of virgin, Zn²⁺ and Co²⁺-doped Ni-ferrites. By doping with Mn²⁺, several secondary phases derived from the SiO₂ matrix accompanied the crystalline spinel ferrite. The crystallite sizes depended on the annealing temperature and type of doping ion. The gradual increase of lattice parameters suggested the uniform distribution of doping metal ions in the NiFe₂O₄ lattice. The saturation magnetization, remanent magnetizations, coercivity, and anisotropy were found to depend on the doping ion, annealing temperature, and particle size. The high saturation magnetization values of the obtained nanocomposites make them suitable for a wide range of applications in the field of sensors development and construction.