Ordered porous nitrogen-doped carbon with atomically dispersed FeN₄ for efficient oxygen reduction reaction in...

It is necessary to develop cost-effective platinum group materials (PGM)-free cathode catalysts for the oxygen reduction reaction (ORR) to replace the state-of-the-art noble metal for the commercialization of microbial fuel cells (MFCs). Fe-N-C catalysts are one of the promising candidates for commercial Pt/C. Herein, a new cost-effective and highly stable Fe-N-C catalyst was designed and successfully prepared via a facile process. The catalyst was prepared through one single thermal conversion from Fe-doped ZIF-8 (zeolitic imidazolate framework), a metal-organic framework (MOF) containing well-defined FeN₄ coordination. The mesopores in the unique structure of MOF promoted efficient mass transfer, while those arising from the pyrolysis of the MOF produced more active sites. Unlike previous preparation methods, post-treatments were avoided here. As a result, the Fe-N-C cathode had a high ORR activity with a half-wave potential (E_1/2) of 0.85 V in a 0.1 M KOH aqueous solution. The classic MFC with this cathodic catalyst provided a maximum power density of up to 1508 mW m^-2.