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Updated: Sep 21, 2025

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Controlled Pd(0)/Ad3P-Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with Ad3P-Coordinated
Jie Dong1,2, Hui Guo1,2, Qiao-Sheng Hu1,2
1Department of Chemistry, College of Staten Island of the City University of New York, Staten Island, New York 10314, United States.
Abstract:
Controlled Pd(0)-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers with tris(1-adamantyl)phosphine (Ad3P) as the ligand was described. Ad3P-coordinated acetanilide-based palladacycle complex (1) was demonstrated to be an efficient initiator for controlled Suzuki cross-coupling polymerization, affording polymers with narrow Đs and well-controlled end groups. Our study provided an efficient ligand and an efficient initiator for controlled Suzuki cross-coupling polymerizations.
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