Heterostructured γ-Fe₂O₃/FeTiO₃ magnetic nanocomposite: An efficient visible-light-driven photocatalyst for the...

The catalyst recovery is the major concern in commercialization of photocatalysts for the industrial effluent treatment process. To overcome this major issue, Fe₂O₃ based magnetic photocatalytic heterostructure ɣ-Fe₂O₃/FeTiO₃ nanocomposite was synthesized by hydrothermal method. Fe₂O₃ is the cheapest visible active magnetic photocatalytic material, but it has the limitation of fast e^-/h + recombination. Titanium (Ti) was loaded on γ-Fe₂O₃ to overcome this issue. The loaded Ti has grown as FeTiO₃ on the surface of ɣ-Fe₂O₃ nanocrystals and emerged as heterostructure ɣ- Fe₂O₃/FeTiO₃ nanocomposites, which was confirmed by XRD and TEM results. The loading concentration of Ti on γ-Fe₂O₃ was optimized to achieve the maximum photocatalytic efficiency without compromising the magnetic property of γ-Fe₂O₃ to facilitate the magnetic separation. DRS-UV spectra revealed the strong visible light response of γ- Fe₂O₃/FeTiO₃ nanocomposite. The photocatalytic efficiencies of the synthesized materials were evaluated using methylene blue (MB) as a model pollutant under sunlight. The built-in electric field between p-n junction between FeTiO₃ and Fe₂O₃ and type II charge transfer mechanism extended the lifetime of the charge carriers at the heterojunction of γ- Fe₂O₃/FeTiO₃, which was confirmed by PL spectra. The vibrating sample magnetometer (VSM) study revealed the decreasing magnetization, coercivity (Hc), and retentivity (Mr) of γ-Fe₂O₃ with increasing concentration of Ti. 92% of the used-up 20 wt% Ti loaded γ-Fe₂O₃/FeTiO₃ magnetic nanocomposite was recovered from the treated wastewater using an electromagnet. Both magnetic properties and efficiency of the nanocomposite increased up to 20 wt% of Ti loading, beyond that decreased due to the increasing composition of antiferromagnetic FeTiO₃ and the increasing number of defect sites as recombination centers. Hence, 20 wt% loading of Ti was concluded as the optimum to enhance the efficiency and to retain the magnetic properties. This work aims the commercialization of magnetic photocatalytic materials for the industrial effluent treatment.