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Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
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Orthogonally deconstructable and depolymerizable polysilylethers via entropy-driven ring-opening metathesis

Alayna M Johnson1, Keith E L Husted1, Landon J Kilgallon1

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139, USA. jaj2109@mit.edu.

Chemical Communications (Cambridge, England)
|July 12, 2022
PubMed
Summary

Researchers developed new deconstructable polysilylethers using entropy-driven ring-opening metathesis polymerization. These polymers exhibit low glass transition temperatures and can be rapidly broken down using specific triggers.

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