Exploring a novel silicone surfactant-based deep eutectic solvent functionalized magnetic iron particles for the...

The current study discussed the use of silicone surfactant-based deep eutectic solvent as a surface modifier for magnetic iron particles (Fe₃O₄) to produce a novel adsorbent and its application for the extraction of organophosphorus pesticides (OPPs) in vegetable samples. A deep eutectic solvent (DES) was prepared using low toxic and inexpensive substances such as silicone surfactant (SS) and dodecanoic acid (DoAc). This new eco-friendly SS:DoAc based DES was explored as a substitution to traditional organic reagents for surface modification of Fe₃O₄ to increase the adsorption capacity and to reduce the matrix interferences, hazardous waste generation and environmental pollution. The newly synthesized SS:DoAc@Fe₃O₄ adsorbent was successfully characterized and applied in magnetic solid phase extraction (MSPE). Under optimized conditions, the proposed approach exhibited excellent linearity ranging from 0.1 to 200 µg/kg (R² ≥ 0.9970), low detection limit (0.03-0.1 µg/kg) and acceptable relative recovery (80-119 %) for the studied OPPs.