Ion exchange fabrication of lanthanide functionalized layered double hydroxides microcapsules for rapid and visual...

Lanthanide ion probes have recently been considered as promising sensing materials due to their high sensitivity and good optical properties. Herein, the 3D hierarchical lanthanide functionalized layered double hydroxides microcapsules were synthesized via a facile ion exchange strategy and further developed as novel fluorescent probes for detecting trace amounts of the anthrax biomarker dipicolinicacid (DPA). Benefiting from the 3D porous superstructure and abundant unsaturated coordination sites of lanthanide ion, the ternary Ni-Fe-Ln-LDHs (Ln = Tb/Eu) not only possess a large reactive contact area to improve the sensitivity of DPA detection, but also demonstrate very fast reaction rate. The design of inexpensive fluorescent test strips can perform the on-site and real-time detection via a smartphone with a color recognition application. More prominently, the sensitivity of the system was evaluated by actual spore samples with the detection limit as low as 3.54 × 10⁴ spores/mL. The 3D lanthanide functionalized LDHs nanoprobe constructed by ion exchange exhibits a new vision for the development of a sensing platform in other research areas.