Insights into the correlation between different adsorption/oxidation/catalytic performance and physiochemical...

Fe-Mn oxide-based composites have been widely used in the solidification of heavy metals or the removal of organic pollutants, which can not only show excellent adsorption/oxidation performance, but also show catalytic activity for common oxidants. At present, the correlation between adsorption/oxidation/catalytic performance and physicochemical characteristics of these composites, and the underlying mechanisms are still unclear. Therefore, the main purpose of this review is to disclose the internal relationship between the physicochemical properties of Fe-Mn oxide-based composites and the pollutant removal performance. From the perspective of crystal phase, the basic units of Fe-Mn oxide composites are divided into Fe-Mn binary oxide (FMBO) and spinel MnFe₂O₄, and the two species were discussed separately in most chapters. The selected physicochemical properties mainly include the type of Fe-Mn oxide composites, surface-to-volume ratio, pore volume, pH_pzc, crystal type, surface functional groups. Because the physicochemical properties that determine how effective Fe-Mn oxide material is at removing contaminants may differ as it performs different functions, we discussed the above problems under different application scenarios (adsorption, oxidation, and advanced oxidation process). Additionally, internal factor (Fe/Mn mole ratio) and external factors (pH_ini, co-ions and ionic strength) were analyzed, and several common synthetic strategies of these composites were presented.