Element doping: a marvelous strategy for pioneering the smart applications of VO₂

Smart materials are leading the future of materials by virtue of their autonomous response behavior to external stimuli; it is widely believed their development and application will bring a new revolution. Among them, vanadium dioxide (VO₂) is a special one showing a unique multi-stimulus responsive metal-insulator transition (MIT) accompanied by a structural phase transition (SPT) with striking changes of physical properties including optical, electrical and thermal properties, etc., making it ideal for smart windows, micro-bolometers, actuators, etc. Since the attractive performances of VO₂ are rooted in MIT behavior (coupled with SPT), element doping becomes a powerful tool in tailoring VO₂ performance. Oriented on the practical requirements, element-doped VO₂ is more promising and competitive in terms of performance, prospect, and cost. Here we focus specifically on element-doped VO₂, the recent progress and potential challenges of which are discussed. We devote attention to the crucial roles of element doping in modulating the properties and driving the practicality of VO₂, aiming to inspire current research to pioneer new applications of VO₂.