A review of datasets and methods for deriving spatiotemporal distributions of atmospheric CO₂

As the most abundant greenhouse gas, atmospheric carbon dioxide (CO₂) is considered one of the main attributors to climate change. Atmospheric CO₂ concentrations can be measured by ground-based monitoring networks, mobile monitoring campaigns, and carbon-observing satellites. However, the worldwide ground-based monitoring networks are composed of sparsely distributed sites and are inadequate to represent the spatiotemporal distributions of CO₂. Satellite-based remote sensing features repeated, long-term, and large-scale measurements, so it plays a crucial role in monitoring the global distributions of atmospheric CO₂. However, due to the presence of heavy clouds (or aerosols) and the limitation of satellite orbiting tracks, there exist large amounts of missing data in satellite retrievals. Various methods, including chemical transport models (CTMs), geostatistical methods, and regression-based models, have been employed to derive full-coverage spatiotemporal distributions of CO₂ based on the limited CO₂ measurements. This review summarizes the strengths and limitations of these methods. However, CTMs simulation results can have high uncertainty due to imperfect knowledge of the real world, and the interpolation accuracy of all geostatistical methods is limited by the large amount of data gaps in current satellite retrieved CO₂ products. To overcome these limitations, regression-based methods (especially machine learning models) have the ability to predict CO₂ with superior predictive performance, so this review also summarizes the framework of the machine learning approach. Leveraging the ongoing advancements of satellite instrumentation, the satellite-based CO₂ products have been improving dramatically in recent decades, and this review will describe and critically assess the advantages and disadvantages of the currently used systems in detail. For future improvements, we recommend the fusion of data from multiple satellite retrievals and CTMs by using machine learning algorithms in order to obtain even longer-term, larger-scale, finer-resolution, and higher-accuracy CO₂ datasets.