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Updated: Aug 28, 2025

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Phase behavior of fluids in undulated nanopores
Martin Pospíšil1, Alexandr Malijevský1
1Department of Physical Chemistry, University of Chemical Technology Prague, Praha 6, 166 28, Czech Republic and The Czech Academy of Sciences, Institute of Chemical Process Fundamentals, Department of Molecular Modelling, 165 02 Prague, Czech Republic.
Abstract:
The geometry of walls forming a narrow pore may qualitatively affect the phase behavior of the confined fluid. Specifically, the nature of condensation in nanopores formed of sinusoidally shaped walls (with amplitude A and period P) is governed by the wall mean separation L as follows. For L>L_{t}, where L_{t} increases with A, the pores exhibit standard capillary condensation similar to planar slits. In contrast, for L
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