Study on Mechanical Properties and High-Speed Impact Resistance of Carbon Nanofibers/Polyurethane Composites Modified...

Polyurethane elastomers (PUE), with superior mechanical properties and excellent corrosion resistance, are applied widely to the protective capability of structures under low-speed impact. However, they are prone to instantaneous phase transition, irreversible deformation and rupture even arising from holes under high-speed impact. In this paper, mussel adhesion proteins were applied to modify carbon nanofibers (CNFs) in a non-covalent way, and creatively mixed with PUE. This can improve the dispersity and interfacial compatibility of nanofillers in the PUE matrix. In addition, the homogeneous dispersion of modified nanofillers can serve as "reinforcing steel bars". The nanofillers and PUE matrix can form "mud and brick" structures, which show superb mechanical properties and impact resistance. Specifically, the reinforcement of 1.0 wt.% modified fillers in PUE is 103.51%, 95.12% and 119.85% higher than the neat PUE in compression modulus, storage modulus and energy absorption capability, respectively. The results have great implications in the design of composite parts for aerospace and army vehicles under extreme circumstances.