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Related Concept Videos

Chirality02:25

Chirality

24.9K
Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
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Chirality in Nature02:30

Chirality in Nature

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
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Properties of Enantiomers and Optical Activity02:24

Properties of Enantiomers and Optical Activity

17.4K
It is essential to understand the difference between chiral and achiral interactions and the implications thereof in optical activity and their applications. Just as our feet, which are chiral, interact uniquely with chiral objects, such as a pair of shoes, but identically with achiral socks, enantiomers of a molecule exhibit different properties only when they interact with other chiral media. An example of a significant implication from this facet is the phenomenon known as optical activity,...
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Prochirality02:05

Prochirality

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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
3.9K
Molecules with Multiple Chiral Centers02:25

Molecules with Multiple Chiral Centers

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Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...
12.0K
¹H NMR Chemical Shift Equivalence: Enantiotopic and Diastereotopic Protons00:58

¹H NMR Chemical Shift Equivalence: Enantiotopic and Diastereotopic Protons

1.9K
Replacing each alpha-hydrogen in chloroethane by bromine (or a different functional group) yields a pair of enantiomers. Such protons are called prochiral or enantiotopic and are related by a mirror plane. Enantiotopic protons are chemically equivalent in an achiral environment. Because most proton NMR spectra are recorded using achiral solvents, enantiotopic hydrogens yield a single signal.
In chiral compounds such as 2-butanol, replacing the methylene hydrogens at C3 produces a pair of...
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Demonstration of Equal-Intensity Beam Generation by Dielectric Metasurfaces
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Angle-selective chiral absorption induced by diffractive coupling in metasurfaces.

Jiaojun Meng, Zhenqing Zhang, Wenxing Liu

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    Researchers developed a chiral metasurface for tunable chiral absorption. This breakthrough uses angle-selective surface plasmon resonance for advanced chiral device applications.

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    Area of Science:

    • Plasmonics and Metamaterials
    • Chiral Optics
    • Nanophotonics

    Background:

    • Chiral metasurfaces are crucial for manipulating light polarization.
    • Achieving tunable and efficient chiral absorption remains a challenge.
    • Existing methods often lack broad spectral tunability or simplicity.

    Purpose of the Study:

    • To demonstrate a simple chiral metasurface for highly efficient and tunable chiral absorption.
    • To explore the underlying mechanism of angle-selective chiral absorption.
    • To highlight the potential of this metasurface for various chiral photonic applications.

    Main Methods:

    • Fabrication of a chiral metasurface using twisted metallic cut-wire arrays.
    • Investigation of chiral absorption properties by varying the incidence angle.
    • Excitation of surface plasmon resonance (SPR) through diffractive effects.

    Main Results:

    • The chiral metasurface achieved highly efficient and continuously tunable chiral absorption.
    • Tunability was realized by simply scanning the incidence angle over a few degrees.
    • Angle-selective chiral absorption was attributed to SPR excited by diffractive effects.

    Conclusions:

    • A simple chiral metasurface enables efficient, angle-tunable chiral absorption over a broad spectrum.
    • This diffraction-assisted approach offers a straightforward strategy for dynamic chiral devices.
    • Potential applications include on-chip chiral detectors, emitters, spectrometers, and lasers.