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Updated: Aug 23, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
3-(2,3-Di-meth-oxy-phen-yl)-2,3-di-hydro-1H-benzo[f]chromen-1-one
1Department of Applied Chemistry, Dongduk Women's University, Seoul 136-714, Republic of Korea.
Abstract:
In the title compound, C21H18O4, the central pyran ring is in an envelope conformation and the dihedral angle between the benzene ring and naphthalene ring system is 88.31 (1)°. The meth-oxy groups at the ortho and meta positions of the benzene ring are tilted to the ring with C-C-O-C torsion angles of 105.9 (4) and 9.5 (5)°, respectively. In the crystal, pairwise C-H⋯O hydrogen bonds form R 2 2(14) inversion dimers, which are linked by another pair of C-H⋯O hydrogen bonds to form [210] chains in the crystal.
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