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2H-[1,3]Thia-zolo[5,4,3-ij]quinolin-3-ium chloride monohydrate
Madeleine A Ehweiner1, Ferdinand Belaj1, Nadia C Mösch-Zanetti1
1University of Graz, Institute of Chemistry, Schubertstr. 1, 8010 Graz, Austria.
Abstract:
The structure of the title hydrated mol-ecular salt, C10H8NS+·Cl-·H2O, obtained by the reaction of sodium quinoline-8-thiolate Na(Quin-8-S) with CH2Cl2 and an aqueous solution of [Bu4N]Cl, contains π-stacked cations [plane-to-plane separation = 3.338 (4)-3.356 (4) Å] and features chains built by alternating Cl- anions and H2O mol-ecules connected by O-H⋯O hydrogen bonds. The cation shows whole-mol-ecule disorder over two flipped orientations in a 0.853 (3):0.147 (3) ratio.
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