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Dicaesium tetra-magnesium penta-kis-(carbonate) deca-hydrate, Cs2Mg4(CO3)5·10H2O
Christine Rincke1, Horst Schmidt1, Wolfgang Voigt1
1Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09599 Freiberg, Germany.
Abstract:
The title carbonate hydrate, Cs2Mg4(CO3)5·10H2O, was crystallized at room temperature out of aqueous solutions containing caesium bicarbonate and magnesium nitrate. Its monoclinic crystal structure (P21/n) consists of double chains of composition 1 ∞[Mg(H2O)2/1(CO3)3/3], isolated [Mg(H2O)(CO3)2]2- units, two crystallographically distinct Cs+ ions and a free water mol-ecule. The crystal under investigation was twinned by reticular pseudomerohedry.
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