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Published on: August 23, 2018
Bis(isonicotinamide-κN)silver(I) tri-fluoro-methane-sulfonate aceto-nitrile disolvate
Rafael A Adrian1, Sara J Ibarra1, Hadi D Arman2
1Department of Chemistry and Biochemistry, University of the Incarnate Word, San Antonio Texas 78209, USA.
Abstract:
The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear mol-ecular geometry. The formation of polymeric chains {[Ag(INAM)2]+} , held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating aceto-nitrile mol-ecules that inter-act the silver metal center via regium bonds.
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