PAHs bound to submicron particles in rural Chinese homes burning solid fuels

Inhalation exposure to polycyclic aromatic hydrocarbons (PAHs) from indoor solid fuel combustion poses a high health risk, and PAHs bound to particles with smaller sizes (e.g., PM_1.0, aerodynamic diameter ≤ 1.0 µm) should be of particular concern since they can penetrate deep into pulmonary alveoli. However, PAHs bound to PM_1.0 was less studied compared with PAHs in total suspended particles or PM_2.5. In this study, multiple provincial field measurements were conducted to investigate 28 PAHs bound to PM_1.0 in rural Chinese homes. Daily averaged PM_1.0-PAH₂₈ concentrations ranged from 27 ng/m³ to 3795 ng/m³ (median: 233 ng/m³) and from 10 ng/m³ to 2978 ng/m³ (median: 87 ng/m³) in indoor and outdoor air, respectively. Higher concentrations were found in northern China in winter due to increased solid fuels consumption for space heating. The ambient pollution was lower during the non-heating season in Eastern China, where clean energy was preferred. Highly toxic congeners were more abundant in indoor air compared with outdoor air. The results of source apportionment revealed that solid fuel combustion was the primary contributor to rural household PM_1.0-PAHs, but other sources such as vehicles cannot be overlooked. The transition to cleaner energy can reduce the indoor PM_1.0-PAH₂₈ and BaP_eq-28 concentrations by 87% and 98%, respectively, and more efficient reduction was observed for highly toxic congeners. The estimated Incremental Lifetime Cancer Risk (ILCR) based on PM_1.0-PAH₂₈ ranged from 4.6 × 10^-5 to 3.4 × 10^-2, far exceeding the acceptable level of 10^-6. Over 60% of the ILCR could be attributed to inhalation exposure during childhood and adolescence.