Evolution of the Microstructure and Phase Composition of the Products Formed in the Reaction between Iridium and W₂B

In the present study, we perform a systematic examination of the products formed by mixing and heating of tungsten boride and iridium powders at different ratios in a broad temperature range using qualitative and quantitative X-ray analysis and time-of-flight neutron diffraction (TOF-ND), in combination with scanning electron microscopy/energy-dispersive spectroscopy (SEM/EDS) performed at different accelerating voltages. The well-known and unknown ternary W-Ir-B phases were detected. The Vickers microhardness value for the new ternary W₂Ir₅B₂ boride was measured. Based on these findings, the ternary W₂Ir₅B₂ boride can be considered hard.