Proximity induced longitudinal and transverse thermoelectric response in graphene-ferromagnetic CrBr₃vdW...

The integration of longitudinal and transverse thermoelectric (TE) fosters various new opportunities in tuning the charge transport behaviour and opens a platform for efficient thermopower devices. The presence of asymmetric electronic structure supposed to accomplish large thermopower and electronic figure of merit. Herein, we investigate magnetic proximity coupled longitudinal and transverse TE behaviour in heterostructure of monolayer semimetal, graphene and a monolayer ferromagnet, CrBr₃under the framework ofab initio-based calculations and employed constant relaxation time approximation (CRTA).The integrated density of states is elevated and asymmetric near Fermi energy region due to seamless proximity integration, depicting mixed character of graphene and CrBr₃. The asymmetric nature of electronic structure significantly affects the Seebeck coefficients (S) and electrical conductivity (σ/τ) of heterostructure. The consistent step-like conductance spectrum influences interfacial polarization due to agile proximity integration. The magnitude of Seebeck coefficient (S) is found to be 653µV K^-1near Fermi level. The heterostructure observes higher electrical conductivity and power factor in n-type region of the order of 10⁶S m^-1and 10²⁰cm^-3at room temperature. The dimensionless electronic figure of merit (zT_e) advocates the heterostructure system to be an ideal TE material. Alongside longitudinal TE, we also find the heterostructure system is sensitive to anomalous Nernst effect (ANE) (transverse TE) with oscillatory nature. The Seebeck and ANE shows high degree of tunability with applied external electric field. The synergistic existence of Seebeck and ANE due to proximity integration in van der Waals atomic crystal at room temperature will provide realistic approach to experimentally fabricate and develop real-time thermopower devices.