Chiroptical induction with prism[5]arene alkoxy-homologs
Xiaotong Liang1, Yanling Shen1, Dayang Zhou2
1College of Architecture and Environment, Huaxi MR Research Center (HMRRC), Department of Radiology, West China Hospital, and Key Laboratory of Green Chemistry & Technology of Ministry of Education, Sichuan University, Chengdu 610064, China. wanght@scu.edu.cn.
Abstract:
The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 107 M-1, significant CD with gabs of up to 0.8 × 10-2 and CPL with glum of 2 × 10-3. The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes.
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