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Updated: Aug 19, 2025

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Conditions for the propulsion of a colloid surrounded by a mesoscale phase separation
Jeanne Decayeux1, Marie Jardat1, Pierre Illien1
1Sorbonne Université, CNRS, Laboratoire PHENIX (Physicochimie des Electrolytes et Nanosystèmes Interfaciaux)), UMR 8234, F-75005 Paris, France.
Abstract:
We study a two-dimensional model of an active isotropic colloid whose propulsion is linked to the interactions between solute particles of the bath. The colloid catalyzes a chemical reaction in its vicinity, that yields a local phase separation of solute particles. The density fluctuations of solute particles result in the enhanced diffusion of the colloid. Using numerical simulations, we thoroughly investigate the conditions under which activity occurs, and we establish a state diagram for the activity of the colloid as a function of the parameters of the model. We use the generated data to unravel a key observable that controls the existence and the intensity of activity: The filling fraction of the reaction area. Remarkably, we finally show that propulsion also occurs in three-dimensional geometries, which confirms the interest of this mechanism for experimental applications.
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