Fabrication of Fe-BTC on aramid fabrics for repeated degradation of isoproturon

Catalytic degradation is a promising and ideal technology in environmental remediation. Among them, catalytic oxidation and photocatalysis respectively based on catalysts and photocatalysts both trigger broad interests because of their high removal activity. However, the reusability of the powder catalysts still faces substantial challenges. Here, a simple strategy is proposed to load Fe-BTC catalyst on aramid fabrics (AF) to construct Fe-BTC MOF @ aramid fabric (Fe-BTC@AF) composite materials with layer-by-layer in situ self-assembly methods. The experimental results illustrated that 98% isoproturon could be removed by Fe-BTC@AF₂₀ with oxidant H₂O₂, while the single Fe-BTC@AF₂₀ could photo-degrade 99% isoproturon within 7 h. Meanwhile, it could sustain a high degradation rate of more than 80%, even if it had gone through 5 degradation cycles. Thus, the Fe-BTC@AF composite has a significant advantage in the recycling ability for degradation of isoproturon, which will have potential applications in the efficient removal of organic contaminants in water.