BaB₂P₂O₈F₂: A Fluoroborophosphate with [B₂P₂O₈F₂]_∞ Layers and Deep-Ultraviolet Cutoff Edge

A fluoroborophosphate, BaB₂P₂O₈F₂, was successfully obtained. Its structure contains a novel [B₂P₂O₈F₂]_∞ layer containing six-membered rings, which is formed by the fundamental building block composed of three types of non-π-conjugated groups, [PO₄], [BO₄], and [BO₂F₂]. BaB₂P₂O₈F₂ has a deep-ultraviolet (DUV) cutoff edge (λ < 200 nm) and a tiny birefringence (Δn = 0.007 at 532 nm), which originates from the constituent non-π-conjugated groups. The title compound enriches the versatility of the fluoroborophosphates, encouraging further research into DUV materials in fluoroborophosphate systems.