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Updated: Aug 14, 2025

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Tris(benzyl-diphenyl-phosphane-κP)(nitrato-κO)silver(I)
Kariska Potgieter1, Frederick P Malan2, Oyekunle Azeez Alimi1
1Department of Chemical Sciences, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa.
Abstract:
The mol-ecular structure of the title complex, [Ag(NO3)(C19H17P)3], exhibits a severely distorted tetra-hedral coordination environment around the central AgI atom, comprising one O and three P atoms. Apart from a primary Ag-O coordination of the nitrato ligand of 2.667 (3) Å, a second (weaker) secondary inter-action of the nitrato ligand via the other O atom of 3.118 (4) Å is observed. The compound crystallizes with a complete mol-ecule in the asymmetric unit. Weak C-H⋯O inter-actions consolidate the packing.
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