Polyelectrolyte Complexes as Desiccants: Thirsty Saloplastics

Desiccants or drying agents are used extensively to remove water from liquids and gases. Many organic reactions, from the laboratory to the industrial scale, are sensitive to even trace amounts of water. A new class of desiccants made from complexed polyelectrolytes, PECs, is described here, exploiting the affinity of charged polymer repeat units for water. The enthalpy of hydration of dry PECs was used for the first time as a quantitative measure of PEC water affinity. Several combinations of positive, Pol⁺, and negative, Pol^-, polymers were used to prepare PECs. All of these displayed significant exothermic (favorable) enthalpies of hydration, measured at room temperature using solution calorimetry. A PEC made from poly(diallyldimethylammonium) and poly(styrene sulfonate) was extruded into convenient shapes. This PEC was used to dry three common solvents, acetonitrile, tetrahydrofuran, and toluene, representing a range of polarities. Added water was radiolabeled with tritium to provide accurate and sensitive detection of residual water after treatment. This PEC was almost as efficient as the comparison desiccants, molecular sieve 3A and calcium sulfate, after 3 days of static drying but could be regenerated at a lower temperature (120 °C) and shed far fewer dust particles.