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XPS Core-Level Chemical Shift by Ab Initio Many-Body Theory

Iskander Mukatayev1, Florient Moevus1, Benoît Sklénard1,2

  • 1Université Grenoble Alpes, CEA, Leti, F-38000, Grenoble, France.

The Journal of Physical Chemistry. A
|February 14, 2023
PubMed
Summary

X-ray photoemission spectroscopy (XPS) reveals atomic composition and chemical bonds. This study identifies classical electrostatics as the primary driver of the chemical shift in XPS, significantly impacting local structure analysis.

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