Facile Control of Ferroelastic Domain Patterns in Multiferroic Thin Films by a Scanning Tip Bias

BiFeO₃, known as the "holy grail of all multiferroics", provides an appealing platform for exploration of multifield coupling physics and design of functional devices. Many fantastic properties of BiFeO₃ are regulated by its ferroelastic domain structure. However, a facile programable control on the ferroelastic domain structure in BiFeO₃ remains challenging and our understanding on the existing control strategies is also far from complete. This work reports a facile control of ferroelastic domain patterns in BiFeO₃ thin films under area scanning poling by exploiting the tip bias as the control parameter. Combining scanning probe microscopy experiments and simulations, we found that BiFeO₃ thin films with pristine 71° rhombohedral-phase stripe domains exhibit at least four switching pathways solely by controlling the scanning tip bias. As a result, one can readily write mesoscopic topological defects into the films without the necessity to change the tip motion. The correlation between conductance of the scanned region and the switching pathway is further investigated. Our results extend the current understanding on the domain switching kinetics and the coupled electronic transport properties in BiFeO₃ thin films. The facile voltage control of ferroelastic domains should facilitate the development of configurable electronic and spintronic devices.