Large area roll-to-roll printed semiconducting carbon nanotube thin films for flexible carbon-based electronics

A universal roll-to-roll (R2R) printing approach was developed to construct large area (8 cm × 14 cm) semiconducting single-walled carbon nanotube (sc-SWCNT) thin films on flexible substrates (such as polyethylene terephthalate (PET), paper, and Al foils) at a printing speed of 8 m min^-1 using highly concentrated sc-SWCNT inks and crosslinked poly-4-vinylphenol (c-PVP) as the adhesion layer. Bottom-gated and top-gated flexible printed p-type TFTs based on R2R printed sc-SWCNT thin films exhibited good electrical properties with a carrier mobility of ∼11.9 cm² V^-1 s^-1, I_on/I_off ratios of ∼10⁶, small hysteresis, and a subthreshold swing (SS) of 70-80 mV dec^-1 at low gate operating voltages (±1 V), and excellent mechanical flexibility. Furthermore, the flexible printed complementary metal oxide semiconductor (CMOS) inverters demonstrated rail-to-rail voltage output characteristics under an operating voltage as low as V_DD = -0.2 V, a voltage gain of 10.8 at V_DD = -0.8 V, and power consumption as low as 0.056 nW at V_DD = -0.2 V. To the best of our knowledge, the electrical properties of the printed SWCNT TFTs (such as I_on/I_off ratio, mobility, operating voltage, and mechanical flexibility) and printed CMOS inverters based on the R2R printed sc-SWCNT active layer in this work are excellent compared to those of R2R printed SWCNT TFTs reported in the literature. Consequently, the universal R2R printing method reported in this work could promote the development of fully printed low-cost, large-area, high-output, and flexible carbon-based electronics.