Antifouling improvement in Pb²⁺ ion selective electrodes by using an environmentally friendly capsaicin derivative

Biofouling is a critical issue for ion selective electrodes (ISE) in complex aqueous systems, seriously compromising the analytical performance of the electrodes (i.e., stability, sensitivity, and lifetime). Herein, an antifouling solid lead ion selective electrode (GC/PANI-PFOA/Pb²⁺-PISM) was successfully prepared by adding propyl 2-(acrylamidomethyl)-3,4,5-trihydroxy benzoate (PAMTB), an environmentally friendly capsaicin derivative, into the ion-selective membrane (ISM). The presence of PAMTB caused no loss in the detection performance of GC/PANI-PFOA/Pb²⁺-PISM (e.g., detection limit (1.9 × 10^-7 M), response slope (28.5 ± 0.8 mV/decade), the response time (20 s), stability (8.6 ± 2.9 μV/s), selectivity and no water layer), whilst imparting an excellent antifouling effect with an antibacterial rate of 98.1% when the content of PAMTB in the ISM was 2.5 wt%. Further, GC/PANI-PFOA/Pb²⁺-PISM maintained stable antifouling properties, excellent potential response, and stability even after soaking in a high-concentration bacterial suspension for 7 days.