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Yulian Zagranyarski1, Diana Valentinova Cheshmedzhieva1, Monika Mutovska1

  • 1Faculty of Chemistry and Pharmacy, Sofia University, 1164 Sofia, Bulgaria.

Sensors (Basel, Switzerland)
|March 30, 2023
PubMed

Keywords:
DFTDiAmSarPET sensorsperylene monoimidesseven membered ring annulation

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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.