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Updated: Aug 4, 2025
Layer-by-layer Synthesis and Transfer of Freestanding Conjugated Microporous Polymer Nanomembranes
Published on: December 15, 2015
A general synthetic method towards conjugated microporous polymers with ordered bicontinuous mesostructures
Qiqi Yang1, Yamei Liu1, Luoxing Xiang1
1School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, Shanghai Key Laboratory of Electrical Insulation and Thermal Ageing, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China. mai@sjtu.edu.cn.
Abstract:
This work demonstrates a universal approach, based on the self-assembly of block copolymers, for the synthesis of novel conjugated microporous polymers (CMPs) with bicontinuous mesostructures. Three hexaazatriphenylene (Aza)-fused CMPs (Aza-CMPs) with double diamond structures were synthesized. The study broadens the spectrum of bicontinuous porous materials and opens a new route for synthesizing CMPs with new topologies.
